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The Goulburn papers (301 items) contain the diplomatic correspondence and official documents of Henry Goulburn, British negotiator of the Treaty of Ghent. The collection includes the official and private letters between the British commissioners and the British Foreign Office, letters between the American and British commissioners, and drafts of the treaty. Included is one of the six original copies of Treaty of Ghent, written in the hand of Henry Clay and signed by each commissioner.

The Goulburn papers (301 items) contain the diplomatic correspondence and treaty drafts of the British and American negotiations for the Treaty of Ghent. The collection includes the letters between the British commissioners and the British foreign office, both official and private, and between the American and British commissioners. These comprise 80 letters, 74 drafts and copies of letters, and various enclosures, treaty drafts, and memoranda. Also present is one of the six original copies of Treaty of Ghent, written in the hand of Henry Clay and signed by each commissioner.

Goulburn and the other British commissioners primarily communicated with Prime Minister Liverpool, Foreign Secretary Lord Castlereagh, and Secretary of War Earl Bathurst, providing them with updates on the negotiation process and receiving instructions and peace guidelines from their superiors. The foreign office also kept the commissioners abreast of military developments in North America, such as the burning of Washington and their defeat at Plattsburgh, New York. Goulburn and his colleagues also exchanged notes, formal gambits, and treaty drafts with the American commissioners ("Ministers Plenipotentiaries") John Quincy Adams, James A. Bayard, Henry Clay, Albert Gallatin, and Jonathan Russell. The collection also contains copies of communications with President James Madison and Secretary of State James Monroe. The negotiations centered on agreements regarding frontier boarders, Native American land guarantees, naval impressments, Atlantic fishery rights, and general maritime rights. Together, these papers document the peace treaty proceedings throughout the fall of 1814, which ultimately led to the settlement at Ghent.

• October 5, 1813: Letter from Baring Ashburton to Lord Castlereagh concerning impressments and preliminaries to the negotiations with America
• November 8, 1813: Letter from St. John's merchants to Sir Richard Goodwin Keats concerning special fishing privileges near Newfoundland for France and the United States
• January 7, 1814: Newspaper clippings reporting peace overtures
• June 29, 1814: A proclamation from President James Madison which refers to the British blockade of the United States a "paper blockade"
• July 18, 1814: A memorial concerning Loyalist Reverend Bennet Allen's claim for lost property
• July 28, 1814: Instructions from Lord Castlereagh of the foreign office to the British Peace Commission containing requests and requirements for peace (14 enclosures)
• August 8, 1814: Protocol of the peace conferences as revised by the British and American commissioners
• August 9, 1814: Report to Castlereagh on preliminary meetings at Ghent, with enclosed letters from President Madison to the American commissioners
• August 14, 1814: Letter from Castlereagh to British commissioners concerning Indians, fisheries, and boundaries
• August 19, 1814: A draft note from British commissioners to the Americans outlining the British peace requirements
• August 24, 1814: The American commissioners rejection of the British terms
• August 30, 1814: Letter enclosing a copy of a note from Castlereagh to James Monroe offering direct negotiations instead of Russian mediation
• September 1, 1814: Letter from Henry Bathurst to Goulburn, rebuking him for almost breaking off negotiations
• September 4, 1814:Draft of the treaty with British alterations
• September 9, 1814: Letter in which the United States rejects the Canadian boundary proposed by Great Britain
• September 16, 1814: Letter from Henry Bathurst to Goulburn concerning pressures to make peace for political reasons in Britain
• September 17, 1814: Letter from Robert Liverpool to Goulburn concerning negotiating for Indian boundaries
• September 19, 1814: Draft letter from British commissioners to American commissioners concerning boundaries and Indian affairs
• October 4, 1814: Letter from Goulburn to Bathurst concerning the burning of Washington and the decision to communicate this intelligence to the American commissioners (response on October 21, 1814)
• October 8, 1814: Letter from British commissioners to American commissioners regarding an ultimatum on the Indian question
• October 13, 1814: Letter from American commissioners to the British commissioners defending the Louisiana Purchase and denying territorial ambitions
• October 18, 1814: Letter from Bathurst to the British commissioners concerning impressments, maritime law, fisheries, and the boundaries of Maine, Niagara, and Michilimackinac
• October 21, 1814: Letter from Liverpool to Goulburn concerning the grave political consequences of continuing the war
• November 10, 1814: American treaty submission with British comments
• November 21, 1814: Letter from Bathurst to Goulburn discussing the effect of Prevost's failure at the Battle of Plattsburgh on the peace process
• November 1814: American commissioners to British commissioners concerning the disposition of prisoners after the peace treaty is signed with an American amendment to article 8 of the treaty
• December 7, 1814: Letter from British commissioners to American commissioners concerning the charge of the British stealing slaves during the war
• December 10, 1814: Letter from British commissioners to Castlereagh concerning verbal alterations in the treaty, technical details, and general progress in negotiations
• December 14, 1814: Letter from British commissioners to Castlereagh concerning copies of the article relating to the Passamaquoddy Islands
• December 14, 1814: Letter from American commissioners to British commissioners concerning the Passamaquoddy Islands and the boundaries on the Mississippi River
• December 26, 1814: Letter from Bathurst to Goulburn congratulating him on the treaty signing
• December 26, 1814: Letter from American commissioners to British commissioners concerning a project for a commercial treaty between the United States and Great Britain
• December 28, 1814: Commercial treaty in the hand of John Quincy Adams
• December 29, 1814: Letter from American commissioners to British commissioners regarding stolen slaves that the British sold in the West Indies
• December 30, 1814: Letter from Goulburn to Bathurst explaining minor changes to the treaty

The collection contains one letter from Goulburn, stationed at the Irish Office, to an unknown recipient concerning Goulburn's interest in representing Cambridge University in the British House of Commons (February 8, 1826).