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The Chapman family papers consist primarily of letters between John W. Chapman of Brooklyn, New York, and his immediate family, written around the turn of the 20th century. Most of the letters relate to his daughter, Sarah Dimon Chapman ("Sallie"), including a series of letters written to her by her mother, Mary C. Chapman, with advice for Sallie's European travels, as well as later letters to John and Mary from Sallie's husband, Lewis Witherbee Francis.

The Chapman family papers contain about 98 items, of which 85 are letters exchanged by members of the Chapman family around the turn of the 20th century. John W. Chapman and his wife, Mary Dimon Chapman, received incoming letters from numerous family members and other acquaintances, such as Mary's father, Charles Dimon. Of the 85 letters, 42 pertain to their daughter Sallie and her husband, Lewis Witherbee Francis. In 1896, Mary Chapman wrote 12 letters to Sallie in which she offered her opinions about several European countries while Sallie was traveling abroad. Her letters occasionally enclose newspaper clippings. Sallie also received letters from her father, grandparents, and other relatives and acquaintances throughout the late 1800s. She and her husband occasionally wrote to her parents, reporting on their health and news from New York City. In one letter, Lewis commented on the stock market and the assassination of President William McKinley (September 15, 1901). A woman who signed herself "Aunt Cordelia" also wrote to John and Mary Chapman on the same subject, sharing her feelings about the shooting and about anarchists (September 8, 1901). Many of these letters are written on stationery with printed letterheads from hotels and businesses, including two of John W. Chapman's professional letterheads.

The collection also contains receipts from Sallie Chapman's purchases in France in July 1896, calling cards, a printed report on the expenses of the Union Pacific System (July 30, 1901), some cat fur kept as a souvenir, and an illustrated newspaper clipping on the Duke and Duchess of Marlborough.